English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Interaction of CFCl3 with an Fe(100) surface part I: Adsorption and X‐ray induced effects at 90 K

MPS-Authors
/persons/resource/persons211638

Grunze,  M.
Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

https://onlinelibrary.wiley.com/doi/epdf/10.1002/bbpc.19810850802
(Any fulltext)

https://doi.org/10.1002/bbpc.19810850802
(Any fulltext)

Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Dowben, P., & Grunze, M. (1981). Interaction of CFCl3 with an Fe(100) surface part I: Adsorption and X‐ray induced effects at 90 K. Berichte der Bunsengesellschaft für physikalische Chemie, 85(8), 728-734. doi:10.1002/bbpc.19810850802.


Cite as: https://hdl.handle.net/21.11116/0000-0001-786F-D
Abstract
We studied the interaction of CFCl3 with an Fe(100) surface over a temperature range from 90‐700 K using surface sensitive techniques. In the first part of our communication we describe adsorption at temperatures below 300 K. Initial adsorption on the clean Fe(100) surface at 90 K is dissociative and is followed by molecular adsorption up to 6 molecular monolayers. Multilayer formation is not expected from the heat of condensation of CFCl3. The adsorption of molecular layers therefore indicates a long‐range stabilization by the substrate of the adsorbate phase. This observation is of general significance of the understanding of extrinsic precursor states in adsorption. We further observe X‐ray induced processes in the adsorbed layer which can be distinguished from thermally induced dissociation.