An XPS study of the composition of thin polyimide films formed by vapor 
deposition

Lamb, R.N.; Baxter, J.; Grunze, M.; Kong, C.W.; Unertl, W.N.

doi:10.1021/la00080a003

Datensatz

DATENSATZ AKTIONENEXPORT

Zur Ablage hinzufügen

Lokale TagsFreigabegeschichteDetailsÜbersicht

Freigegeben

Zeitschriftenartikel

An XPS study of the composition of thin polyimide films formed by vapor deposition

MPG-Autoren

/persons/resource/persons211638

Grunze, M.
Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society;

Externe Ressourcen

https://pubs.acs.org/doi/pdf/10.1021/la00080a003
(beliebiger Volltext)

https://doi.org/10.1021/la00080a003
(beliebiger Volltext)

Volltexte (beschränkter Zugriff)

Für Ihren IP-Bereich sind aktuell keine Volltexte freigegeben.

Volltexte (frei zugänglich)

Es sind keine frei zugänglichen Volltexte in PuRe verfügbar

Ergänzendes Material (frei zugänglich)

Es sind keine frei zugänglichen Ergänzenden Materialien verfügbar

Zitation

Lamb, R., Baxter, J., Grunze, M., Kong, C., & Unertl, W. (1988). An XPS study of the composition of thin polyimide films formed by vapor deposition. Langmuir, 4(2), 249-256. doi:10.1021/la00080a003.

Zitierlink: https://hdl.handle.net/21.11116/0000-0001-8933-B

Zusammenfassung

Films of polyimide (>8 nm) were formed on a polycrystalline silver surface following heating of a vapor-deposited layer of 4,4,-oxydianiline (ODA) and 1,2,4,5-benzenetetracarboxylic anhydride (PMDA). The imidization reaction leading to polymer formation was followed in situ with X-ray photoelectron spectroscopy. The uncertainties inherent in a quantitative analysis of the composition of the top 8 nm of the surface layer (corresponding to the sampling depth of the technique) are discussed with respect to thick films of ODA and PMDA adsorbed on a clean Cu(lll) surface at 200 K. The fully cured polyimide film contains excess ODA-like and PMDA-like constituents as trapped molecules or terminal groups.