Second-harmonic generation applied to the formation of ultrathin organic films 
on inorganic substrates

Grunze, M.; Buck, M.

doi:10.1007/978-3-642-84933-6_6

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Second-harmonic generation applied to the formation of ultrathin organic films on inorganic substrates

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Grunze, M.
Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Grunze, M., & Buck, M. (1993). Second-harmonic generation applied to the formation of ultrathin organic films on inorganic substrates. In R. F. Howe, R. N. Lamb, & K. Wandelt (Eds.), Surface Science (pp. 67-77). Berlin, Heidelberg: Springer.

Cite as: https://hdl.handle.net/21.11116/0000-0001-992A-4

Abstract

In this article we describe the application of second harmonic generation (SHG) to study the formation of self-assembled n-alkyl thiol films from solution with respect to their adsorption kinetics. As will be shown, the submonolayer sensitivity of SHG allows to determine quantitatively the coverage of an adsorbate in situ and in real time. That SHG is a technique which allows also to discriminate between reactions at the interface and ordering processes occurring during three-dimensional film growth will be demonstrated by experiments on the formation of vapor deposited polyamic acid films on gold and silver substrates.