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A Purely Organic Tricarbanion

MPS-Authors
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Höfler,  Denis
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lingnau,  Julia B.
Service Department Farès (NMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Nöthling,  Nils
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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List,  Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Höfler, D., Goddard, R., Lingnau, J. B., Nöthling, N., & List, B. (2018). A Purely Organic Tricarbanion. Angewandte Chemie International Edition, 57(27), 8326-8329. doi:10.1002/anie.201803647.


Cite as: http://hdl.handle.net/21.11116/0000-0001-AF53-D
Abstract
How many carbanions can an organic molecule accommodate? The formation of purely organic carbanions with multiple charges is challenging as charge stabilization cannot be achieved through metal coordination. Previously, only quaternary ammonium dicarbanion salts had been reported. By using highly electron-deficient trifluoromethane-sulfonyl (triflyl or Tf) groups,the formation of apurely organic tricarbanion has been realized for the first time.