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Journal Article

Two Amphoteric Silver Carbene Clusters

MPS-Authors
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Tskhovrebov,  Alexander G.
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Goddard,  Richard
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Fürstner,  Alois
Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Tskhovrebov, A. G., Goddard, R., & Fürstner, A. (2018). Two Amphoteric Silver Carbene Clusters. Angewandte Chemie International Edition, 57(27), 8089-8094. doi:10.1002/anie.201803246.


Cite as: https://hdl.handle.net/21.11116/0000-0001-BF6B-1
Abstract
Two highly labile silver carbene cluster complexes are described, which are unique in that they mark the transition point at which the carbene center transmutes from a fairly common NHC‐like nucleophilic behavior to an electrophilic character befitting reactive silver carbene intermediates of relevance in various catalytic transformations. This amphoteric character is the distinguishing attribute of a μ‐bridged donor/donor carbene entity that connects two silver atoms of triangular or tetrahedral metallic core units.