Synthesis and characterization of self-assembled monolayers based on 
redox-active silane compounds on platinum surfaces

Long, Yi-Tao; Herrwerth, Sascha; Eck, Wolfgang; Grunze, Michael

doi:10.1039/B107091F

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Synthesis and characterization of self-assembled monolayers based on redox-active silane compounds on platinum surfaces

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Grunze, Michael
Cellular Biophysics, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Long, Y.-T., Herrwerth, S., Eck, W., & Grunze, M. (2002). Synthesis and characterization of self-assembled monolayers based on redox-active silane compounds on platinum surfaces. Physical Chemistry Chemical Physics, 4(3), 522-526. doi:10.1039/B107091F.

Cite as: https://hdl.handle.net/21.11116/0000-0001-BE21-4

Abstract

A novel alkanesilane (3-triethoxysilyl)propyl-carbamic acid 6-(9,10-dioxo-9,10-dihydro-anthracen-1-yloxy)-hexyl ester)(TESA), with a redox-active anthraquinone head group was shown to form self-assembled monolayers on a platinum oxide surface, without the use of a silane coupling agent. The TESA monolayers were characterized by X-ray electron spectroscopy (XPS), reflection–absorption infrared spectroscopy (IRRAS), and electrochemical methods.