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Cyclopropyl fatty acids implicate a radical but not a cation as an intermediate in P450BM3-catalysed hydroxylations.

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Cryle,  Max
Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Cryle, M., Stuthe, J. M. U., Ortiz de Montellano, P. R., & De Voss, J. J. (2004). Cyclopropyl fatty acids implicate a radical but not a cation as an intermediate in P450BM3-catalysed hydroxylations. Chemical Communications, 7(5), 512-513. doi:10.1039/B315911F.


Cite as: http://hdl.handle.net/21.11116/0000-0001-EE16-B
Abstract
Novel cyclopropyl containing fatty acids are good substrates for P450(BM3) catalysed hydroxylation and analysis of their oxidation products indicates the presence of a radical intermediate (maximum rebound rate 2.6 x 10(10) s(-1)) and the absence of any cationic intermediate.