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Reactor Design and Kinetic Study on Adsorption/Desorption of CO and Cl2 for Industrial Phosgene Synthesis

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Bähr,  Alexander
Research Group Tüysüz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Moon,  Gun-Hee
Research Group Tüysüz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Tüysüz,  Harun
Research Group Tüysüz, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Bähr, A., Moon, G.-H., Diedenhoven, J., Kiecherer, J., Barth, E., & Tüysüz, H. (2018). Reactor Design and Kinetic Study on Adsorption/Desorption of CO and Cl2 for Industrial Phosgene Synthesis. Chemie-Ingenieur-Technik, 90(10), 1513-1519. doi:10.1002/cite.201800016.


Cite as: https://hdl.handle.net/21.11116/0000-0002-55A1-8
Abstract
The aim of this work is the utilization of carbon monoxide (CO) from steel mill gases for the synthesis of phosgene, which can further react with phenol to building blocks for polymers. The effect of impurities like NOx, CO2, and O2 on the activity and stability of the activated‐carbon (AC) catalyst and the follow‐up products should be evaluated. Therefore, new porous carbon catalysts and a new reactor are designed for a systematic kinetic study on the adsorption and desorption behaviors of CO and chlorine (Cl2) on carbon‐based materials to identify AC catalysts with optimum physical properties