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Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming

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Carbonio,  Emilia
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;
Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, BESSY II;

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Hävecker,  Michael
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Knop-Gericke,  Axel
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Köpfle, N., Götsch, T., Grünbacher, M., Carbonio, E., Hävecker, M., Knop-Gericke, A., et al. (2018). Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming. Angewandte Chemie International Edition, 57(44), 14613-14618. doi:10.1002/anie.201807463.


Cite as: https://hdl.handle.net/21.11116/0000-0002-8934-9
Abstract
C‐saturated Pd0 nanoparticles with an extended phase boundary to ZrO2 evolve from a Pd0Zr0 precatalyst under CH4 dry reforming conditions. This highly active catalyst state fosters bifunctional action: CO2 is efficiently activated at oxidic phase boundary sites and PdxC provides fast supply of C‐atoms toward the latter.