English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
  Local TagsRelease HistoryDetailsSummary

Released
Journal Article

Electronic properties of two isomeric charge transfer [2.2]paracyclophanes

MPS-Authors
/persons/resource/persons95265

Schweitzer,  Dieter
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons93336

Hausser,  Karl H.
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons211097

Taglieber,  Volker K.
Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons95446

Staab,  Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Schweitzer, D., Hausser, K. H., Taglieber, V. K., & Staab, H. A. (1976). Electronic properties of two isomeric charge transfer [2.2]paracyclophanes. Chemical Physics, 14(2), 183-187. doi:10.1016/0301-0104(76)80037-7.


Cite as: https://hdl.handle.net/21.11116/0000-0002-A5D4-4
Abstract
The emission spectra and the zero field splitting parameters of the two diastereomeric 4,7-dicyano-12,15-dimethoxy-[2.2] paracyclophanes 3 and 4 in comparison to the corresponding monomers 1 and 2 were investigated in order to study the orientation dependence of charge transfer (CT) interactions. The general results in glasses (PMMA) are: broad structureless emission bands with large spectral overlap between fluorescence and phosphorescence; strong reduction of the zero field splitting parameters D and D* by a factor of two for the pseudo-ortho isomer 3 and by a factor of four for the pseudo-geminal isomer 4 showing the strong effect of the geometrical orientation. In single crystals of the same phanes the zero field parameters were found to be further reduced to about one fifth of the value of the monomers which indicates, in accordance with the emission spectra, an additional intermolecular interaction between adjacent phanes.