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Journal Article

Indirectly transmitted charge‐transfer interactions: multilayered [2.2] paracyclophane quinhydrones

MPS-Authors
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Staab,  Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Zapf,  Udo
Max Planck Institute for Medical Research, Max Planck Society;

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Gurke,  Anneliese
Max Planck Institute for Medical Research, Max Planck Society;

External Resource

https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.197708011
(Any fulltext)

https://doi.org/10.1002/anie.197708011
(Any fulltext)

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Citation

Staab, H. A., Zapf, U., & Gurke, A. (1977). Indirectly transmitted charge‐transfer interactions: multilayered [2.2] paracyclophane quinhydrones. Angewandte Chemie, 16(11), 801-803. doi:10.1002/anie.197708011.


Cite as: https://hdl.handle.net/21.11116/0000-0002-D562-F
Abstract
[2.2] Paracyclophane quinhydrones with intercalated benzene rings have now been synthesized for the first time in the form of their methyl ethers (1) and (2). Their broad CT band must be due to an intramolecular CT transition; the charge is transmitted in “vertical conjugation” through the π‐electron system of the benzene. Orientation dependence of the CT absorption as observed in simple donor‐acceptor 2.2 paracyclophanes is almost completely absent.
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