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Copper(I) Complexes with Anionic Acylthio‐ or Acylselenourea Ligands and N‐Heterocyclic Carbenes or Phosphanes

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Rust,  Jörg
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Lehmann,  Christian W.
Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Kuchar, J., Rust, J., Lehmann, C. W., & Mohr, F. (2018). Copper(I) Complexes with Anionic Acylthio‐ or Acylselenourea Ligands and N‐Heterocyclic Carbenes or Phosphanes. European Journal of Inorganic Chemistry, 2018(48), 5215-5222. doi:10.1002/ejic.201801007.


Cite as: http://hdl.handle.net/21.11116/0000-0003-2657-1
Abstract
Copper(I) complexes containing acylthio‐ and selenoureato ligands can be accessed either by transmetallation from the corresponding silver compounds or by direct reaction of the acylthio/selenourea with a copper(I) precursor in the presence of base. Several examples of tricoordinate organocopper(I) complexes containing N‐heterocyclic carbenes as well as tetrahedral bis(phosphane) copper(I) compounds are reported with their spectroscopic and structural characterization.