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Journal Article

V2Se: a novel antifluorite-type cubic phase with a metal-metal bonding

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Ryu,  Gihun
Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Ryu, G., & Dinh Duong, L. (2019). V2Se: a novel antifluorite-type cubic phase with a metal-metal bonding. Dalton Transactions, 48(24), 8556-8559. doi:10.1039/c9dt01569h.


Cite as: https://hdl.handle.net/21.11116/0000-0003-F55D-1
Abstract
A new antifluorite-type (Li2O-type) cubic compound, V2Se, has been synthesized for the first time by changing the amount of selenium in chemical vapor transport. The vanadium-based cubic phase studied here reveals a metal-metal bonding feature in the electronic band structure. This compound is the first example of an antifluorite-type cubic structure in a V-Se system.