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Abstract

The mechanism of superconductivity in cuprates remains one of the big challenges of condensed matter physics. High-T-c cuprates crystallize into a layered perovskite structure featuring copper oxygen octahedral coordination. Due to the Jahn Teller effect in combination with the strong static Coulomb interaction, the octahedra in high-T-c cuprates are elongated along the c axis, leading to a 3dx(2)-y(2) orbital at the top of the band structure wherein the doped holes reside. This scenario gives rise to 2D characteristics in high-T-c cuprates that favor d-wave pairing symmetry. Here, we report superconductivity in a cuprate Ba2CuO4-y,wherein the local octahedron is in a very exceptional compressed version. The Ba2CuO4-y compound was synthesized at high pressure at high temperatures and shows bulk superconductivity with critical temperature (T-c) above 70 K at ambient conditions. This superconducting transition temperature is more than 30 K higher than the T-c for the isostructural counterparts based on classical La2CuO4. X-ray absorption measurements indicate the heavily doped nature of the Ba2CuO4-y superconductor. In compressed octahedron, the 3d3z(2)-r(2) orbital will be lifted above the 3dx(2)-y(2) orbital, leading to significant 3D nature in addition to the conventional 3dx(2)-y(2) orbital. This work sheds important light on advancing our comprehensive understanding of the superconducting mechanism of high T-c in cuprate materials.