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Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes

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Schucht,  Heike
Research Department Neese, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Citation

Meyer, N., Schucht, H., Lehmann, C. W., Weibert, B., Winter, R. F., & Mohr, F. (2017). Multimetallic Gold-Iron Compounds Based on Aurated Ferrocenes. European Journal of Inorganic Chemistry, (2), 521-526. doi:10.1002/ejic.201601458.


Cite as: https://hdl.handle.net/21.11116/0000-0006-E1AB-B
Abstract
A family of aurated ferrocenes was prepared by a transmetallation reaction using ferroceneboronic acid derivatives. With this method, multimetallic ferrocenyl complexes [FcAu(PPh3)] {Fc = (eta(5)-C5H4)FeCp} and [(mu-P-P)(AuFc)(2)] {P-P = dppe, dppf}, as well as 1,1'-diaurated ferrocenes [Fe(eta(5)-C5H4AuPPh3)(2)] and [Fe{(eta(5)-C5H4Au)}(2)(mu-P-P)] {P-P = dppe, dppf}, were obtained in high yields as air-stable orange materials. The compounds were characterised by spectroscopic methods, cyclic voltammetry and single-crystal X-ray diffraction. The reactivity of the dinuclear gold(I) complex in oxidative addition reactions is also reported.