Catalytic Isofunctional Reactions—Expanding the Repertoire of Shuttle and 
Metathesis Reactions

Bhawal, Benjamin N.; Morandi, Bill

doi:10.1002/anie.201803797

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Catalytic Isofunctional Reactions—Expanding the Repertoire of Shuttle and Metathesis Reactions

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Bhawal, Benjamin N.
Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Laboratorium für Organische Chemie, ETH Zürich;

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Morandi, Bill
Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society;
Laboratorium für Organische Chemie, ETH Zürich;

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Citation

Bhawal, B. N., & Morandi, B. (2019). Catalytic Isofunctional Reactions—Expanding the Repertoire of Shuttle and Metathesis Reactions. Angewandte Chemie International Edition, 58(30), 10074-10103. doi:10.1002/anie.201803797.

Cite as: https://hdl.handle.net/21.11116/0000-0004-53C1-4

Abstract

Transfer hydrogenation, alkene metathesis, and alkyne metathesis possess great value to the synthetic chemistry community. One of the key features of these processes is their reversibility, which can be attributed to the presence of the same number and type of functional groups in both the reactants and products, making these reactions isofunctional. These classic reactions have recently inspired the development of novel shuttle and metathesis reactions that offer great promise for synthetic chemistry. This Review describes and systematically categorizes both recent and older examples of shuttle and metathesis reactions other than transfer hydrogenation and alkene/alkyne metathesis.