Electronic, Structural and Functional Versatility in 
Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks

Castells-Gil, J.; Mañas-Valero, S.; Vitórica-Yrezábal, I. J.; Ananias, D.; Rocha, J.; Santiago, R.; Bromley, S. T.; Baldovi, J.; Coronado, E.; Soutoa, M.; Espallargasa, G. M.

doi:10.1002/chem.201902855

Item

ITEM ACTIONSEXPORT

Add to Basket

Please note that a newer version of this item is available:
https://pure.mpg.de/pubman/item/item_3149224_7

DetailsSummary

Released

Journal Article

Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks

MPS-Authors

/persons/resource/persons214173

Baldovi, J.
Theory Group, Theory Department, Max Planck Institute for the Structure and Dynamics of Matter, Max Planck Society;

External Resource

https://doi.org/10.1002/chem.201902855
(Publisher version)

https://chemrxiv.org/articles/Electronic_Structural_and_Functional_Versatility_in_Tetrathiafulvalene-Lanthanide_Metal-Organic_Frameworks/9037352
(Preprint)

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

theo_theo_2019_espallargas_chemistry.pdf
(Postprint), 2MB

Supplementary Material (public)

There is no public supplementary material available

Citation

Castells-Gil, J., Mañas-Valero, S., Vitórica-Yrezábal, I. J., Ananias, D., Rocha, J., Santiago, R., et al. (2019). Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks. Chemistry – A European Journal, 25(54), 12636-12643. doi:10.1002/chem.201902855.

Cite as: https://hdl.handle.net/21.11116/0000-0004-5AB8-8

Abstract

Tetrathiafulvalene-Lanthanide (TTF-Ln) Metal-Organic Frameworks (MOFs) are an interesting class of multifunctional materials in which porosity can be combined with electronic properties such as electrical conductivity, redox activity, luminescence and magnetism. Herein we report a new family of isostructural TTF-Ln MOFs, denoted as MUV-5(Ln) (Ln = Gd, Tb, Dy, Ho, Er), exhibiting semiconducting properties as a consequence of the short intermolecular S···S contacts established along the chain direction between partially oxidised TTF moieties. In addition, this family shows photoluminescence properties and single-molecule magnetic behaviour, finding near-infrared (NIR) photoluminescence in the Yb/Er derivative and slow relaxation of the magnetisation in the Dy and Er derivatives. As such properties are dependent on the electronic structure of the lanthanide ion, we emphasise the immense structural, electronic and functional versatility of this class of materials.
Introduction