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Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework

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van Gastel,  Maurice
Research Group van Gastel, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Sharma, M. K., Rottschäfer, D., Blomeyer, S., Neumann, B., Stammler, H.-G., van Gastel, M., et al. (2019). Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework. Chemical Communications, 55(70), 10408-10411. doi:10.1039/C9CC04701H.


Cite as: https://hdl.handle.net/21.11116/0000-0004-91EE-C
Abstract
The synthesis and characterization of the crystalline diphosphene radical cations [{(NHC)C(Ph)}P]2(GaCl4) (NHC = IPr = C{(NDipp)CH}2 3, SIPr = C{(NDipp)CH2}2 4; Dipp = 2,6-iPr2C6H3) and dications [{(NHC)C(Ph)}P]2(GaCl4)2 (NHC = IPr 5, SIPr 6) featuring a π-conjugated C2P2C2-framework has been reported.