Detection of deuterium quadrupole splittings by odendor in the excited triplet 
state of benzophenone

Wäckerle, Gerhard; Dinse, Klaus−Peter

doi:10.1016/0009-2614(81)85267-0

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Detection of deuterium quadrupole splittings by odendor in the excited triplet state of benzophenone

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Wäckerle, Gerhard
Max Planck Institute for Medical Research, Max Planck Society;

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Dinse, Klaus−Peter
Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Wäckerle, G., & Dinse, K. (1981). Detection of deuterium quadrupole splittings by odendor in the excited triplet state of benzophenone. Chemical Physics Letters, 78(3), 598-602. doi:10.1016/0009-2614(81)85267-0.

Cite as: https://hdl.handle.net/21.11116/0000-0004-F72B-6

Abstract

Using a fully deuterated sample of benzophenone, optically detected ENDOR transitions reveal line splittings due to deuterium quadrupole interaction in the excited triplet state. The line splittings were used to determine the ring-carbonyl-ring bond angle 2θ = 138(1.5)° and the phenyl-ring twist ansle ψ = 28.5(1.5)° of benzophenone in its metastable excited state.