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Journal Article

Cation-induced charge-transfer absorptions of oligooxa[n.n]paracyclophane quinhydrones

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Bauer,  Helmut
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Briaire,  Jan
Max Planck Institute for Medical Research, Max Planck Society;

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Staab,  Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Bauer, H., Briaire, J., & Staab, H. A. (1985). Cation-induced charge-transfer absorptions of oligooxa[n.n]paracyclophane quinhydrones. Tetrahedron Letters, 26(50), 6175-6178. doi:10.1016/S0040-4039(00)95045-7.


Cite as: https://hdl.handle.net/21.11116/0000-0005-64CC-5
Abstract
Intramolecular [n.n]paracyclophane quinhydrones with two oligo= oxaalkylene bridges 2a–e (m = 0,1,2,3 and 4, resp.) have been synthesized. The selective double complexation of these compounds with metal cations of suitable size (e.g. 7) is indicated by remarkable enhancements of the intensity of charge-transfer absorptions.