Bis(tricarbonyliron) complexes of P -quinodimethanes: fragmentation and 
isomerisation under electron impact

Rentzea, Marina; Koray, Ali R.; Staab, Heinz A.

doi:10.1016/S0040-4039(00)98837-3

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Bis(tricarbonyliron) complexes of P -quinodimethanes: fragmentation and isomerisation under electron impact

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Rentzea, Marina
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Staab, Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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https://www.sciencedirect.com/science/article/pii/S0040403900988373/pdf?md5=b43d0aab8270e207ddf5cab9adf517dc&pid=1-s2.0-S0040403900988373-main.pdf
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Citation

Rentzea, M., Koray, A. R., & Staab, H. A. (1985). Bis(tricarbonyliron) complexes of P -quinodimethanes: fragmentation and isomerisation under electron impact. Tetrahedron Letters, 26(21), 2563-2566. doi:10.1016/S0040-4039(00)98837-3.

Cite as: https://hdl.handle.net/21.11116/0000-0005-6ECF-8

Abstract

EI mass spectra of -η4,η4-[3,6-bis(methylene)-1,4-cyclohexadiene]-bis=(tricarbonyliron) complexes , are reported. The fragmentation pathway is rationalized by assuming a rearrangement of the -bis(tricarbonyliron) complexes into the -isomers under electron impact.