English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

In Situ Induction of Strain in Iron Phosphide (FeP2) Catalyst for Enhanced Hydroxide Adsorption and Water Oxidation

MPS-Authors
/persons/resource/persons220452

Li,  Guowei
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons230811

Yang,  Qun
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons209329

Fu,  Chenguang
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126525

Auffermann,  Gudrun
Gudrun Auffermann, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons179670

Sun,  Yan
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126601

Felser,  Claudia
Claudia Felser, Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

External Resource
No external resources are shared
Fulltext (restricted access)
There are currently no full texts shared for your IP range.
Fulltext (public)

Li_In-situ-induction.pdf
(Publisher version), 3MB

Supplementary Material (public)
There is no public supplementary material available
Citation

Li, G., Yang, Q., Rao, J., Fu, C., Liou, S.-C., Auffermann, G., et al. (2020). In Situ Induction of Strain in Iron Phosphide (FeP2) Catalyst for Enhanced Hydroxide Adsorption and Water Oxidation. Advanced Functional Materials, 1907791, pp. 1-8. doi:10.1002/adfm.201907791.


Cite as: https://hdl.handle.net/21.11116/0000-0005-9553-5
Abstract
Carbon-based materials have been widely used in heterogeneous catalysis because of their advantages of high surface area, thermal stability, and chemical inertness. However, their role in the catalysis is not fully understood although most studies conclude that the coupling between the carbon support and catalyst could reduce the charge transfer resistance and improve the kinetics of catalytic reactions such as water splitting. In this study, a carbon-modified FeP2 electrocatalyst with a one-step strategy is synthesized. The tensile strain is introduced in situ in the ab crystal plane of the FeP2 catalyst. This leads to charge redistribution between H and O atoms in the OH bonds and enhances the adsorption of reaction intermediates. In the water oxidation process, this results in a decrease in the energy barrier for the rate-determining step, specifically, the chemical step of *OH adsorption preceded by one-electron transfer. Benefiting from the optimized adsorption energy, the strained catalysts exhibit excellent oxygen evolution reaction (OER) activity with a low overpotential in addition to their increased stability. This study provides a new strategy for the introducing of strains in functional materials and provides new insights into the influence of carbon modification on OER activity.