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Journal Article

Thickening of T-1 Precipitates during Aging of a High Purity Al-4Cu-1Li-0.25Mn Alloy


Hetaba,  Walid
Research Department Schlögl, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Häusler, I., Kamachali, R. D., Hetaba, W., & Skrotzki, B. (2019). Thickening of T-1 Precipitates during Aging of a High Purity Al-4Cu-1Li-0.25Mn Alloy. Materials, 12(1): 30. doi:10.3390/ma12010030.

Cite as: https://hdl.handle.net/21.11116/0000-0005-DDB8-3
The age hardening response of a high-purity A1-4Cu-1Li-0.25Mn alloy (wt. %) during isothermal aging without and with an applied external load was investigated. Plate shaped nanometer size T-1 (Al2CuLi) and theta' (Al2Cu) hardening phases were formed. The precipitates were analyzed with respect to the development of their structure, size, number density, volume fraction and associated transformation strains by conducting transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) studies in combination with geometrical phase analysis (GPA). Special attention was paid to the thickening of T-1 phase. Two elementary types of single-layer T-1 precipitate, one with a Li-rich (Type 1) and another with an Al-rich (Defect Type 1) central layer, were identified. The results show that the Defect Type 1 structure can act as a precursor for the Type 1 structure. The thickening of T-1 precipitates occurs by alternative stacking of these two elementary structures. The thickening mechanism was analyzed based on the magnitude of strain associated with the precipitation transformation normal to its habit plane. Long-term aging and aging under load resulted in thicker and structurally defected T-1 precipitates. Several types of defected precipitates were characterized and discussed. For theta' precipitates, a ledge mechanism of thickening was observed. Compared to the normal aging, an external load applied to the peak aged state leads to small variations in the average sizes and volume fractions of the precipitates.