Dibenz[a,j]anthracene via Photo‐cyclodehydrogenation of 
9,10‐Dihydro‐2‐styrylphenanthrene

Diederich, Francois Nico; Schneider, Karin; Staab, Heinz A.

doi:10.1002/cber.19841170339

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Dibenz[a,j]anthracene via Photo‐cyclodehydrogenation of 9,10‐Dihydro‐2‐styrylphenanthrene

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Diederich, Francois Nico
Max Planck Institute for Medical Research, Max Planck Society;

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Schneider, Karin
Max Planck Institute for Medical Research, Max Planck Society;

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Staab, Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Diederich, F. N., Schneider, K., & Staab, H. A. (1984). Dibenz[a,j]anthracene via Photo‐cyclodehydrogenation of 9,10‐Dihydro‐2‐styrylphenanthrene. Chemische Berichte, 117(3), 1255-1258. doi:10.1002/cber.19841170339.

Cite as: https://hdl.handle.net/21.11116/0000-0005-A37F-5

Abstract

Dibenz[a,j]anthracen durch Photocyclodehydrierung von 9,10‐Dihydro‐2‐styrylphenanthren

Während aus 2‐Styrylphenanthren (1) durch Photocyclodehydrierung Benzo[c]chrysen (2) entsteht, läßt sich unter Ausnutzung der „ΣF*‐Regel”︁5) aus 9,10‐Dihydro‐2‐styrylphenanthren (4) durch Photocyclodehydrierung zu 6 und anschließende Dehydrierung Dibenz[a,j]anthracen (3) erhalten.