Synthesis of a Porphyrin Sandwiched between Two Parallel p‐Benzoquinone Units

Weiser, Jürgen; Staab, Heinz A.

doi:10.1002/anie.198406231

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Synthesis of a Porphyrin Sandwiched between Two Parallel p‐Benzoquinone Units

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Weiser, Jürgen
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Staab, Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Weiser, J., & Staab, H. A. (1984). Synthesis of a Porphyrin Sandwiched between Two Parallel p‐Benzoquinone Units. Angewandte Chemie, International Edition, 23(8), 623-625. doi:10.1002/anie.198406231.

Cite as: https://hdl.handle.net/21.11116/0000-0005-AF1F-5

Abstract

p‐Benzoquinone‐porphyrin‐p‐benzoquinone is the layer sequence in the sandwich compound shown on the cover. This compound is formed in 0.1% yield from 1, RCHO and pyrrole in refluxing propionic acid. The four bridges in the sandwich compound are short and contain no heteroatoms. It may serve as a model for the study of biochemically important electron‐transfer reactions.