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Synthesis of a porous C3N-derived-framework with high yield by gallic acid cross-linking using salt melts

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Tian,  Zhihong
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Heil,  Tobias
Nadezda V. Tarakina, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Antonietti,  Markus
Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society;

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Tian, Z., Heil, T., Schmidt, J., Cao, S., & Antonietti, M. (2020). Synthesis of a porous C3N-derived-framework with high yield by gallic acid cross-linking using salt melts. ACS Applied Materials and Interfaces, 12(11), 13127-13133. doi:10.1021/acsami.9b20478.


Cite as: https://hdl.handle.net/21.11116/0000-0005-B89B-D
Abstract
Porous carbon/nitrogen frameworks are an emerging class of noble organic materials with wide range of potential applications. However, the design and controlled synthesis of those materials is still a challenge. Herein, we present the rational design of such a system with high microporosity, specific surface areas of up to 946 m2 g-1, and excellent condensation yields. The obtained noble frameworks were used for the delivery of larger organic molecules and changed the melting behavior of some daily drug molecules along their highly polarizable surface.