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Journal Article

Acid promoted radical-chain difunctionalization of styrenes with stabilized radicals and (N,O)-nucleophiles

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Liu,  Sensheng
Research Group Klußmann, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Klussmann,  Martin
Research Group Klußmann, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

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Citation

Liu, S., & Klussmann, M. (2020). Acid promoted radical-chain difunctionalization of styrenes with stabilized radicals and (N,O)-nucleophiles. Chemical Communications, 56(10), 1557-1560. doi:10.1039/C9CC09369A.


Cite as: https://hdl.handle.net/21.11116/0000-0005-DB4C-0
Abstract
A difunctionalization of alkenes through sequential addition of a radical and a nucleophile has been developed, which is suggested to proceed by a radical chain mechanism not requiring a catalyst. An electron transfer step to the oxidant benzoyl peroxide is facilitated by protonation with a strong acid.