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The study of microwave-induced nuclear polarization in the sensitized trans-cis isomerization of fumaronitrile

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Bagryanskaya, E., Avdievich, N., Grishin, Y., & Sagdeev, R. (1989). The study of microwave-induced nuclear polarization in the sensitized trans-cis isomerization of fumaronitrile. Chemical Physics, 135(1), 123-129. doi:10.1016/0301-0104(89)87011-9.


Cite as: http://hdl.handle.net/21.11116/0000-0006-44E1-F
Abstract
The effects of stimulated (SNP) and dynamic nuclear polarization (DNP) in the photosensitized fumaronitrile isomerization in the presence of naphthalene have been studied in the magnetic field range from 0.5 to 50 mT. The ESR spectra of short-lived radical pairs of the type have been detected using the SNP method. The manifestations of the electron exchange in SNP and DNP have been studied and the rate constant of the exchange has been estimated.