Tuning of Electronic and Vibrational Properties of Transition Metal Selenides 
TSe2 (T = Os, Ru) and Their Metallization under High Pressure

Naumov, P. G.; Baskakov, A. O.; Starchikov, S. S.; Lyubutin, I. S.; Ogarkova, Yu. L.; Lyubutina, M. V.; Barkalov, O. I.; Medvedev, S. A.

doi:10.1134/S0021364020080044

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Tuning of Electronic and Vibrational Properties of Transition Metal Selenides TSe₂ (T = Os, Ru) and Their Metallization under High Pressure

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Naumov, P. G.
Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

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Citation

Naumov, P. G., Baskakov, A. O., Starchikov, S. S., Lyubutin, I. S., Ogarkova, Y. L., Lyubutina, M. V., et al. (2020). Tuning of Electronic and Vibrational Properties of Transition Metal Selenides TSe₂ (T = Os, Ru) and Their Metallization under High Pressure. JETP Letters, 111(8), 456-462. doi:10.1134/S0021364020080044.

Cite as: https://hdl.handle.net/21.11116/0000-0006-4E41-A

Abstract

We present a systematic analysis of electrical properties of two transition metal selenides OsSe2 and RuSe2 under conditions of low temperature down to 1.8K and external pressure up to 43 GPa. Both compounds have a pyrite-type crystal structure under ambient conditions and, according to Raman spectroscopy, do not undergo phase transitions up to the highest pressures. OsSe2 and RuSe2 undergo semiconductor-to-metal transitions at pressures up to 15 GPa. Further increase in pressure leads to the appearance of a superconducting transition at low temperatures. At 40 GPa, the critical temperatures of the superconducting transition reach maximum values of 5.5 and 6K for RuSe2 and OsSe2, respectively. © 2020, Pleiades Publishing, Inc.