Studies of various mechanisms of nuclear polarisation due to a resonant 
high-frequency field in radical reactions

Bagryanskaya, EG; Grishin, YA; Avdievich, NI; Sagdeev, RZ; Molin, YN

doi:10.1016/0009-2614(86)80318-9

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Studies of various mechanisms of nuclear polarisation due to a resonant high-frequency field in radical reactions

MPS-Authors

There are no MPG-Authors in the publication available

External Resource

https://www.sciencedirect.com/science/article/pii/0009261486803189
(Publisher version)

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Bagryanskaya, E., Grishin, Y., Avdievich, N., Sagdeev, R., & Molin, Y. (1986). Studies of various mechanisms of nuclear polarisation due to a resonant high-frequency field in radical reactions. Chemical Physics Letters, 128(2), 162-167. doi:10.1016/0009-2614(86)80318-9.

Cite as: http://hdl.handle.net/21.11116/0000-0006-4BC0-D

Abstract

Two different mechanisms of creation of nuclear polarisation in radical reaction products are studied by means of the high-frequency field influence on intermediate radical pairs (stimulated nuclear polarisation, SNP) and on intermediate short-lived radicals (dynamic nuclear polarisation, DNP). Criteria are formulated for distinguishing the contributions of DNP and SNP effects, and experimental demonstration of this possibility is presented for photoinduced reactions of quinones.