Synthesis of a Macrobicyclic Thiazolium‐Host and Supramolecular Catalysis of 
the Benzoin Condensation

Lutter, Heinz-Dieter; Diederich, François

doi:10.1002/anie.198611251

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Synthesis of a Macrobicyclic Thiazolium‐Host and Supramolecular Catalysis of the Benzoin Condensation

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Lutter, Heinz-Dieter
Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Lutter, H.-D., & Diederich, F. (1986). Synthesis of a Macrobicyclic Thiazolium‐Host and Supramolecular Catalysis of the Benzoin Condensation. Angewandte Chemie International Edition, 25(12), 1125-1127. doi:10.1002/anie.198611251.

Cite as: https://hdl.handle.net/21.11116/0000-0006-916A-F

Abstract

The macrobicyclic compound 1, a model for thiamine pyrophosphate‐dependent enzymes , exhibits extremely high catalytic activity in the benzoin condensation. This effect can be ascribed to the cavity in 1 , which is large enough to complex two benzaldehyde molecules.