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Journal Article

Radical cations and anions of s-tetrazines: an electron spin resonance study

MPS-Authors
/persons/resource/persons198522

Fischer,  Hans
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Umminger,  Irmgard
Max Planck Institute for Medical Research, Max Planck Society;

/persons/resource/persons94523

Neugebauer,  Franz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

https://pubs.rsc.org/en/content/articlepdf/1986/c3/c39860000837
(Any fulltext)

https://doi.org/10.1039/C39860000837
(Any fulltext)

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Citation

Fischer, H., Umminger, I., Neugebauer, F. A., Chandra, H., & Symons, M. C. R. (1986). Radical cations and anions of s-tetrazines: an electron spin resonance study. Journal of the Chemical Society, Chemical Communications, 1986(11), 837-838. doi:10.1039/C39860000837.


Cite as: https://hdl.handle.net/21.11116/0000-0006-92AF-0
Abstract
Liquid- and solid-state studies of the radical cations and anions of s-tetrazine and various derivatives thereof show that the anions have a π-SOMO concentrated on the four ring nitrogen atoms whilst all but the (–NMe2)2 derivative form σ-cations, again with the SOMO confined to the four nitrogen atoms.