Cyclo[d.e.d.e.e.d.e.d.e.e. ]decakisbenzene, a New Cycloarene

Funhoff, Dirk; Staab, Heinz A.

doi:10.1002/anie.198607421

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Cyclo[d.e.d.e.e.d.e.d.e.e. ]decakisbenzene, a New Cycloarene

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Funhoff, Dirk
Max Planck Institute for Medical Research, Max Planck Society;

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Staab, Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Funhoff, D., & Staab, H. A. (1986). Cyclo[d.e.d.e.e.d.e.d.e.e. ]decakisbenzene, a New Cycloarene. Angewandte Chemie International Edition, 25(8), 742-744. doi:10.1002/anie.198607421.

Cite as: https://hdl.handle.net/21.11116/0000-0006-92FD-8

Abstract

The new parent hydrocarbon 1 is the second cycloarene (after kekulene) that consists of twelve symmetrically arranged benzene rings. 1 forms yellow crystals and was prepared by photocyclization of a partially hydrogenated benzophenanthrenophanediene. Compound 1 contains 40 π electrons, but can be formulated with an inner and an outer [4n + 2] π‐electron perimeter.