English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Zintl Defects in Intermetallic Clathrates

MPS-Authors
/persons/resource/persons126529

Baitinger,  Michael
Michael Baitinger, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126538

Böhme,  Bodo
Bodo Böhme, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126896

Wagner,  Frank R.
Frank Wagner, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

/persons/resource/persons126841

Schwarz,  Ulrich
Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society;

External Resource
No external resources are shared
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Baitinger, M., Böhme, B., Wagner, F. R., & Schwarz, U. (2020). Zintl Defects in Intermetallic Clathrates. Zeitschrift für anorganische und allgemeine Chemie, 646(14), 1034-1041. doi:10.1002/zaac.202000107.


Cite as: http://hdl.handle.net/21.11116/0000-0006-980C-2
Abstract
Dedicated to Prof. Yuri Grin on the Occasion of his 65th Birthday In many cases, idealized crystal structure models cannot rationalize the actual properties of intermetallic compounds. For a realistic approach in materials research, microstructures and defects need to be taken into account. In case of clathrate compounds, particularly the intrinsic framework vacancies (denoted as Zintl defects) demand consideration. Consequently, clathrate research produces evidence that modern-day structure chemistry involves the utilization of advanced X-ray diffraction methods combined with elaborated bulk phase analyses, the investigation of phase relations, and the study of mutual interrelations in the triangle chemical bonding–structure–properties. Herein, we review some fundamental contributions to the specific defect chemistry of intermetallic clathrates. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH Co. KGaA.