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Synthesis, structure and electrical properties of the two-dimensional organic conductor, (BEDT-TTF)2BrI2

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Gärtner,  Stephan
Max Planck Institute for Medical Research, Max Planck Society;

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Schweitzer,  Dieter
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Daoben, Z., Ping, W., Meixiang, W., Zhaolou, Y., Nailue, Z., Gärtner, S., et al. (1986). Synthesis, structure and electrical properties of the two-dimensional organic conductor, (BEDT-TTF)2BrI2. Physica B-Condensed Matter, 143(1-3), 281-284. doi:10.1016/0378-4363(86)90118-X.


Cite as: https://hdl.handle.net/21.11116/0000-0006-ACD0-D
Abstract
Single crystals of α-(BEDT-TTF)2BrI2 and β-(BEDT-TTF)2BrI2 were prepared using standard electrochemical techniques in nitrogen saturated benzonitrile using containing (n-C4H10)NBrI2 as supporting electrolyte. The crystals have nearly identical structure features of α-(BEDT-TTF)2I3 and β-(BEDT-TTF)2I3, except that the BrI−2 anions are disordered in α-(BEDT-TTF)2BrI2 and β-(BEDT-TTF)2BrI2. Their electrical behavior is different from the corresponding α-,β-(BEDT-TTF)2I3 species.