The structure of the underpotential deposition of copper on to Pt(111) in the 
presence of chloride anions: a LEED structure analysis

Bludau, Horst; Wu, Kai; Zei, Mau-Scheng; Eiswirth, Markus; Over, Herbert; Ertl, Gerhard

doi:10.1016/S0039-6028(97)01061-3

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The structure of the underpotential deposition of copper on to Pt(111) in the presence of chloride anions: a LEED structure analysis

MPS-Authors

/persons/resource/persons21375

Bludau, Horst
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons249327

Wu, Kai
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22283

Zei, Mau-Scheng
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21488

Eiswirth, Markus
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21934

Over, Herbert
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21498

Ertl, Gerhard
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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引用

Bludau, H., Wu, K., Zei, M.-S., Eiswirth, M., Over, H., & Ertl, G. (1998). The structure of the underpotential deposition of copper on to Pt(111) in the presence of chloride anions: a LEED structure analysis. Surface Science, 402(1-3), 786-789. doi:10.1016/S0039-6028(97)01061-3.

引用: https://hdl.handle.net/21.11116/0000-0006-C320-9

要旨

The underpotential deposition (UPD) of copper on to Pt(111) in the presence of chloride anions was studied by full-dynamical LEED-intensity analyses. A deformed (4×4) LEED pattern was observed at an emersion potential of 0.36 V vs. Ag/AgCl, right in between the two characteristic and well-separated peaks of the cyclic voltammogram (CV). Corresponding LEED intensity measurements and simulations of the integral-order beams indicate that the UPD of Cu forms a single pseudomorphic Cu layer on Pt(111).