Cine-Substitutions at Five-Membered Hetarenes Enabled by Sulfonium Salts

Berger, Florian; Alvarez, Eva Maria; Frank, Nils; Bohdan, Kostiantyn; Kondratiuk, Mykhailo; Torkowski, Luca; Engl, Pascal S.; Barletta, Joana; Ritter, Tobias

doi:10.1021/acs.orglett.0c02067

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Cine-Substitutions at Five-Membered Hetarenes Enabled by Sulfonium Salts

MPS-Authors

/persons/resource/persons230059

Berger, Florian
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons247990

Alvarez, Eva Maria
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Frank, Nils
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons243568

Bohdan, Kostiantyn
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons243566

Kondratiuk, Mykhailo
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons249783

Torkowski, Luca
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons240803

Engl, Pascal S.
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

Barletta, Joana
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons198096

Ritter, Tobias
Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Berger, F., Alvarez, E. M., Frank, N., Bohdan, K., Kondratiuk, M., Torkowski, L., et al. (2020). Cine-Substitutions at Five-Membered Hetarenes Enabled by Sulfonium Salts. Organic Letters, 22(14), 5671-5674. doi:10.1021/acs.orglett.0c02067.

Cite as: https://hdl.handle.net/21.11116/0000-0006-D560-D

Abstract

We report a nucleophilic substitution reaction of five-membered hetarylsulfonium salts that results in a change of the substitution pattern on the arene. The products of these cine-substitutions are hard to access synthetically otherwise. The sulfonium salts that serve as starting materials are generated by a highly site-selective C–H functionalization reaction.