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Journal Article

Light emission during the agglomeration of silver clusters in noble gas matrices

MPS-Authors
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Rabin,  Irene
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Schulze,  Wilfried
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Ertl,  Gerhard
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Rabin, I., Schulze, W., & Ertl, G. (1998). Light emission during the agglomeration of silver clusters in noble gas matrices. The Journal of Chemical Physics, 108(12), 5137-5142. doi:10.1063/1.475919.


Cite as: https://hdl.handle.net/21.11116/0000-0006-F6AA-5
Abstract
The agglomeration of small silver clusters in noble gas matrices to form larger ones may be accompanied by the emission of light. Spectral analysis reveals that part of radiation intensity can be attributed to fluorescence from excited metal atoms, dimers and trimers the formation of which results from cluster/cluster agglomeration as a consequence of the gain in binding energy. The remaining spectral features must be assigned to excited clusters Agn, with n⩾4.