Cationic phosphorus–carbon–pnictogen cages isolobal to [C5R5]+

Fish, Cheryl; Green, Michael; Kilby, Richard J.; Lynam, Jason M.; McGrady, John E.; Pantazis, Dimitrios A.; Russell, Christopher A.; Willans, Charlotte E.

doi:10.1039/B517710C

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Cationic phosphorus–carbon–pnictogen cages isolobal to [C₅R₅]⁺

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Fish, C., Green, M., Kilby, R. J., Lynam, J. M., McGrady, J. E., Pantazis, D. A., et al. (2006). Cationic phosphorus–carbon–pnictogen cages isolobal to [C₅R₅]⁺. Chemical Communications, (13), 1375-1377. doi:10.1039/B517710C.

Cite as: https://hdl.handle.net/21.11116/0000-0007-2ED3-8

Abstract

The cationic cages nido-[C₂Bu^t₂P₂E]⁺ (E = As, Sb), which are isolobal to the cyclopentadienyl cation, adopt square based pyramidal structures with the heavy pnictogen atom at the apex; NMR and computational methods have been used to probe the dynamic behaviour of the complexes.