Concerted [2+2] Cycloaddition of Alkenes to a Ruthenium–Phosphorus Double Bond

Derrah, Eric J.; Pantazis, Dimitrios A.; McDonald, Robert; Rosenberg, Lisa

doi:10.1002/anie.201000356

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Concerted [2+2] Cycloaddition of Alkenes to a Ruthenium–Phosphorus Double Bond

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Derrah, E. J., Pantazis, D. A., McDonald, R., & Rosenberg, L. (2010). Concerted [2+2] Cycloaddition of Alkenes to a Ruthenium–Phosphorus Double Bond. Angewandte Chemie International Edition, 49(19), 3367-3370. doi:10.1002/anie.201000356.

Cite as: https://hdl.handle.net/21.11116/0000-0007-3113-C

Abstract

A square deal for Ru=PR₂: The Ru=PR₂ π bond in a terminal phosphido complex undergoes regio‐ and stereoselective [2+2] cycloaddition reactions of alkenes to yield metallaphosphacyclobutanes (see structure; P red, Ru yellow, C gray), which are analogous to olefin metathesis intermediates.