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Concerted [2+2] Cycloaddition of Alkenes to a Ruthenium–Phosphorus Double Bond

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Citation

Derrah, E. J., Pantazis, D. A., McDonald, R., & Rosenberg, L. (2020). Concerted [2+2] Cycloaddition of Alkenes to a Ruthenium–Phosphorus Double Bond. Angewandte Chemie International Edition, 49(19), 3367-3370. doi:10.1002/anie.201000356.


Cite as: http://hdl.handle.net/21.11116/0000-0007-3113-C
Abstract
A square deal for Ru=PR2: The Ru=PR2 π bond in a terminal phosphido complex undergoes regio‐ and stereoselective [2+2] cycloaddition reactions of alkenes to yield metallaphosphacyclobutanes (see structure; P red, Ru yellow, C gray), which are analogous to olefin metathesis intermediates.