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Selective hydrodeoxygenation of hydroxyacetophenones to ethyl-substituted phenol derivatives using a FeRu@SILP catalyst

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Goclik,  Lisa
Research Department Leitner, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Offner-Marko,  Lisa Ramona
Research Department Leitner, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Bordet,  Alexis
Research Department Leitner, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Leitner,  Walter
Research Department Leitner, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;
Institut für Technische Chemie und Makromolekulare Chemie, Rheinisch‐Westfälische Technische Hochschule Aachen, Worringer Weg 1, 52074 Aachen, Germany;

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Citation

Goclik, L., Offner-Marko, L. R., Bordet, A., & Leitner, W. (2020). Selective hydrodeoxygenation of hydroxyacetophenones to ethyl-substituted phenol derivatives using a FeRu@SILP catalyst. Chemical Communications, 56(66), 9509-9512. doi:10.1039/d0cc03695a.


Cite as: http://hdl.handle.net/21.11116/0000-0007-A70B-1
Abstract
The selective hydrodeoxygenation of hydroxyacetophenone derivatives is achieved opening a versatile pathway for the production of valuable substituted ethylphenols from readily available substrates. Bimetallic iron ruthenium nanoparticles immobilized on an imidazolium-based supported ionic liquid phase (Fe25Ru75@SILP) show high activity and stability for a broad range of substrates without acidic co-catalysts.