Applications of electron paramagnetic resonance spectroscopy to heavy 
main-group radicals

Cutsail III, George E.

doi:10.1039/d0dt02436h

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Applications of electron paramagnetic resonance spectroscopy to heavy main-group radicals

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Cutsail III, George E.
Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Citation

Cutsail III, G. E. (2020). Applications of electron paramagnetic resonance spectroscopy to heavy main-group radicals. Dalton Transactions, 49(35), 12128-12135. doi:10.1039/d0dt02436h.

Cite as: https://hdl.handle.net/21.11116/0000-0007-8546-4

Abstract

The exploration of heavy main-group radicals is rapidly expanding, for which electron paramagnetic resonance (EPR) spectroscopic characterisation plays a key role. EPR spectroscopy has the capacity to deliver information of the radical's electronic, geometric and bonding structure. Herein, foundations of electron-nuclear hyperfine analysis are detailed before reviewing more recent applications of EPR spectroscopy to As, Sb, and Bi centred radicals. Additional diverse examples of the application of EPR spectroscopy to other heavy main group radicals are highlighted.