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Journal Article

A metastable Ru(III)azido complex with metallo-Staudinger reactivity

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Bill,  Eckhard
Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Citation

Park V, S., Fry, C. G., Bill, E., & Berry, J. F. (2020). A metastable Ru(III)azido complex with metallo-Staudinger reactivity. Chemical Communications, 56(73), 10738-10741. doi:10.1039/d0cc04426a.


Cite as: https://hdl.handle.net/21.11116/0000-0007-D33D-7
Abstract
The metastable purple [(Py5Me2)Ru-III(N-3)](2+)ion reacts with PPh(3)at room temperature to form the phosphinimine complex [(Py5Me2)Ru-II(N(H)PPh3)](2+)and free [H2NPPh3](+)in a combined 23% conversion. Mechanistic studies suggest that this is the first metallo-Staudinger reaction of a late transition metal that bypasses the nitrido mechanism and instead utilizes a Ru-N=N=N-PPh(3)phosphazide intermediate.