English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Journal Article

Coordination polymers of Ag(i) and Hg(i) ions with 2,2 '-azobispyridine: synthesis, characterization and enhancement of conductivity in the presence of Cu(ii) ions

MPS-Authors
/persons/resource/persons237747

Weyhermüller,  Thomas
Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

External Ressource
No external resources are shared
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Maity, S., Naskar, K., Bhowmik, T., Bera, A., Weyhermüller, T., Sinha, C., et al. (2020). Coordination polymers of Ag(i) and Hg(i) ions with 2,2 '-azobispyridine: synthesis, characterization and enhancement of conductivity in the presence of Cu(ii) ions. Dalton Transactions, 49(25), 8438-8442. doi:10.1039/d0dt01470b.


Cite as: http://hdl.handle.net/21.11116/0000-0007-D2EC-2
Abstract
The cationic coordination polymers (CPs) of the types [Hg-2(abpy)(2)](n)[PF6](2n)(1) and [Ag(abpy)](n)[PF6](n)(2) (abpy = 2,2 '-azobispyridine) were synthesized and characterized. Experimentation using the crystals confirmed that1and2are conductors of electricity. The relative conductivity of1is 62 times greater than that of2. The conductivity of1increases 70 fold when it reacts with Cu(2+)ions.