Coordination polymers of Ag(i) and Hg(i) ions with 2,2 '-azobispyridine: 
synthesis, characterization and enhancement of conductivity in the presence of 
Cu(ii) ions

Maity, Suvendu; Naskar, Kaushik; Bhowmik, Tanmay; Bera, Amalendu; Weyhermüller, Thomas; Sinha, Chittaranjan; Ghosh, Prasanta

doi:10.1039/d0dt01470b

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Coordination polymers of Ag(i) and Hg(i) ions with 2,2 '-azobispyridine: synthesis, characterization and enhancement of conductivity in the presence of Cu(ii) ions

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Weyhermüller, Thomas
Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Citation

Maity, S., Naskar, K., Bhowmik, T., Bera, A., Weyhermüller, T., Sinha, C., et al. (2020). Coordination polymers of Ag(i) and Hg(i) ions with 2,2 '-azobispyridine: synthesis, characterization and enhancement of conductivity in the presence of Cu(ii) ions. Dalton Transactions, 49(25), 8438-8442. doi:10.1039/d0dt01470b.

Cite as: https://hdl.handle.net/21.11116/0000-0007-D2EC-2

Abstract

The cationic coordination polymers (CPs) of the types [Hg-2(abpy)(2)](n)[PF6](2n)(1) and [Ag(abpy)](n)[PF6](n)(2) (abpy = 2,2 '-azobispyridine) were synthesized and characterized. Experimentation using the crystals confirmed that1and2are conductors of electricity. The relative conductivity of1is 62 times greater than that of2. The conductivity of1increases 70 fold when it reacts with Cu(2+)ions.