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Journal Article

Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO2 Using a Molecular Cobalt(II) Triazine Complex

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Cramer,  Hanna H.
Research Department Leitner, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Chatterjee,  Basujit
Research Department Leitner, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Weyhermüller,  Thomas
Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Werlé,  Christophe
Research Department Leitner, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;

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Leitner,  Walter
Research Department Leitner, Max Planck Institute for Chemical Energy Conversion, Max Planck Society;
Institut für Technische Chemie und Makromolekulare Chemie, Rheinisch‐Westfälische Technische Hochschule Aachen, Worringer Weg 1, 52074 Aachen, Germany;

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Citation

Cramer, H. H., Chatterjee, B., Weyhermüller, T., Werlé, C., & Leitner, W. (2020). Controlling the Product Platform of Carbon Dioxide Reduction: Adaptive Catalytic Hydrosilylation of CO2 Using a Molecular Cobalt(II) Triazine Complex. Angewandte Chemie, International Edition in English, 59(36), 15674-15681. doi:10.1002/anie.202004463.


Cite as: https://hdl.handle.net/21.11116/0000-0007-853E-E
Abstract
The catalytic reduction of carbon dioxide (CO2) is considered a major pillar of future sustainable energy systems and chemical industries based on renewable energy and raw materials. Typically, catalysts and catalytic systems are transforming CO2 preferentially or even exclusively to one of the possible reduction levels and are then optimized for this specific product. Here, we report a cobalt-based catalytic system that enables the adaptive and highly selective transformation of carbon dioxide individually to either the formic acid, the formaldehyde, or the methanol level, demonstrating the possibility of molecular control over the desired product platform.