Floquet engineering of molecular dynamics via infrared coupling

Reitz, Michael; Genes, Claudiu

doi:10.1063/5.0033382

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Floquet engineering of molecular dynamics via infrared coupling

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Reitz, Michael
Genes Research Group, Research Groups, Max Planck Institute for the Science of Light, Max Planck Society;
International Max Planck Research School, Max Planck Institute for the Science of Light, Max Planck Society;

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Genes, Claudiu
Genes Research Group, Research Groups, Max Planck Institute for the Science of Light, Max Planck Society;

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https://aip.scitation.org/doi/10.1063/5.0033382
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Citation

Reitz, M., & Genes, C. (2020). Floquet engineering of molecular dynamics via infrared coupling. The Journal of Chemical Physics, 153: 234305. doi:10.1063/5.0033382.

Cite as: https://hdl.handle.net/21.11116/0000-0007-425D-7

Abstract

We discuss Floquet engineering of dissipative molecular systems through periodic driving of an infrared-active vibrational transition, either directly or via a cavity mode. Following a polaron quantum Langevin equations approach, we derive correlation functions and stationary quantities showing strongly modified optical response
of the infrared-dressed molecule. The coherent excitation of molecular vibrational modes, in combination with the modulation of electronic degrees of freedom due to vibronic coupling can lead to both enhanced
vibronic coherence as well as control over vibrational sideband amplitudes. The additional coupling to an infrared cavity allows for the controlled suppression of undesired sidebands, an effect stemming from the Purcell enhancement of vibrational relaxation rates.