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Conference Paper

Interaction of lanthanum(III) chloride with zeolites under anhydrous conditions

MPS-Authors

Sulikowski,  Bogdan
Fritz Haber Institute, Max Planck Society;

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Find,  Josef
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Karge,  Hellmut G.
Chemical Physics, Fritz Haber Institute, Max Planck Society;

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Herein,  Daniel
Inorganic Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Sulikowski, B., Find, J., Karge, H. G., & Herein, D. (1998). Interaction of lanthanum(III) chloride with zeolites under anhydrous conditions. In Polish-German Zeolite Colloquium (pp. 323-340). Nicholas Copernicus University Press.


Cite as: http://hdl.handle.net/21.11116/0000-0007-5B2C-3
Abstract
Interaction of lanthanum(III) chloride with hydrogen forms of ferrierite, mordenite, zeolite L, and faujasite, under completely anhydrous conditions, is described. The course of the interaction has been studied by in situ i.r. and XRD techniques. No evidence of interaction between LaCl3 and small-pore H-ferrierite was found. The other three structures investigated do interact with LaCl3even under the complete exclusion of water or water vapor from the surroundings. Plausible mechanisms of the solid-state ion exchange in zeolites are also discussed.