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Substrate Mediated Photodissociation of NO2/N2O4 Adsorbed on Pd(111)

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Hasselbrink,  Eckart
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Nettesheim,  Stefan
Fritz Haber Institute, Max Planck Society;

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Wolf,  Martin
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Ertl,  Gerhard
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

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Citation

Hasselbrink, E., Nettesheim, S., Wolf, M., Cassuto, & Ertl, G. (1990). Substrate Mediated Photodissociation of NO2/N2O4 Adsorbed on Pd(111). In G. Betz, & P. Varga (Eds.), Desorption Induced by Electronic Transitions DIET IV: Proceedings of the Fourth International Workshop, Gloggnitz, Austria, October 2–4, 1989 (pp. 75-79). Berlin: Springer.


Cite as: https://hdl.handle.net/21.11116/0000-0008-30C2-6
Abstract
UV irradiation (hv = 3.5 to 6.4 eV) of NO2/N2O4 adsorbed on top of a NO covered Pd(111) surface leads to photodissociation. State-resolved detection of the NO molecules released into the gas phase and determination of the yield as function of angle and polarization provide clear evidence that the dominant primary process consists in electronic excitation of the metallic substrate rather than in direct absorption by the adsorbate.