English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT

Released

Book Chapter

Substrate Mediated Photodissociation of NO2/N2O4 Adsorbed on Pd(111)

MPS-Authors
/persons/resource/persons252305

Hasselbrink,  Eckart
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons252307

Nettesheim,  Stefan
Fritz Haber Institute, Max Planck Society;

/persons/resource/persons22250

Wolf,  Martin
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

/persons/resource/persons21498

Ertl,  Gerhard
Physical Chemistry, Fritz Haber Institute, Max Planck Society;

External Resource
No external resources are shared
Fulltext (public)
There are no public fulltexts stored in PuRe
Supplementary Material (public)
There is no public supplementary material available
Citation

Hasselbrink, E., Nettesheim, S., Wolf, M., Cassuto, & Ertl, G. (1990). Substrate Mediated Photodissociation of NO2/N2O4 Adsorbed on Pd(111). In G. Betz, & P. Varga (Eds.), Desorption Induced by Electronic Transitions DIET IV: Proceedings of the Fourth International Workshop, Gloggnitz, Austria, October 2–4, 1989 (pp. 75-79). Berlin: Springer.


Cite as: http://hdl.handle.net/21.11116/0000-0008-30C2-6
Abstract
UV irradiation (hv = 3.5 to 6.4 eV) of NO2/N2O4 adsorbed on top of a NO covered Pd(111) surface leads to photodissociation. State-resolved detection of the NO molecules released into the gas phase and determination of the yield as function of angle and polarization provide clear evidence that the dominant primary process consists in electronic excitation of the metallic substrate rather than in direct absorption by the adsorbate.