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Synthesis, molecular structure, and electron-donor properties of pseudogemd,8,l4,17-Tetrakis(dimethylamino)[3.3]paracyclophane

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Staab,  Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Gabel,  Günter
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Krieger,  Claus
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Staab, H. A., Gabel, G., & Krieger, C. (1987). Synthesis, molecular structure, and electron-donor properties of pseudogemd,8,l4,17-Tetrakis(dimethylamino)[3.3]paracyclophane. Chemische Berichte, 120(3), 269-273. doi:10.1002/cber.19871200304.


Cite as: http://hdl.handle.net/21.11116/0000-0007-99A0-7
Abstract
The title compound 1 consisting of two N,N,N′,N′‐tetramethyl‐p‐phenylenediamine (TMPD) units in a [3.3]paracyclophane system has been synthesized starting from 2 via 3–10 and 13. The molecular structure of 1 is discussed on the basis of an X‐ray structure analysis. Electron‐donor properties of 1 are reported.