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Electron donor‐acceptor compounds, 46 molecular structures and charge‐transfer absorptions of [2.2]‐, [3.3]‐, and [4.4] paracyclophanes with tetracyanobenzene as acceptor unit

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Staab,  Heinz A.
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Krieger,  Claus
Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society;

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Wahl,  Peter
Max Planck Institute for Medical Research, Max Planck Society;

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Kay,  Kwang-Yol
Max Planck Institute for Medical Research, Max Planck Society;

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Citation

Staab, H. A., Krieger, C., Wahl, P., & Kay, K.-Y. (1987). Electron donor‐acceptor compounds, 46 molecular structures and charge‐transfer absorptions of [2.2]‐, [3.3]‐, and [4.4] paracyclophanes with tetracyanobenzene as acceptor unit. Chemische Berichte, 120(4), 551-558. doi:10.1002/cber.19871200415.


Cite as: http://hdl.handle.net/21.11116/0000-0007-99D8-9
Abstract
Based on X‐ray analyses the molecular structures of the electron donor‐acceptor [2.2]‐ and [3.3]paracyclophanes 1, 2, 4, 6, 10, and 11 are discussed in terms of steric and electronic effects. The charge‐transfer absorptions of 1–9 were measured and are dealt with in correlation to the variation of the strength of the electron donors and of the donor‐acceptor distances in the series 1–9.